Dr. Aude DEMESSENCE. Formation

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1 Dr. Aude DEMESSENCE French Nationality Born the 13 th July 1980 Institut Lavoisier de Versailles Collège de France, Paris Formation From Dec Nov Nov Oct June 2003 Oct June 2003 Institut Lavoisier, Université de Versailles Saint Quentin en Yvellines, Versailles and Laboratoire de Chimie de la Matière Condensée, Collège de France, Paris, France Postdoctoral Fellow in Soft/Surface Chemistry Supervisors, Dr. Christian SERRE and Dr. Clément SANCHEZ Project: From Porous Metal-Organic Frameworks Colloidal Suspensions to Nanoporous Thin Films. Department of Chemistry, University of California, Berkeley, USA Postdoctoral Fellow in Coordination Chemistry Supervisor, Pr. Jeffrey R. LONG Project: Metal-Organic Frameworks for Hydrogen Storage, Carbon Dioxide Capture and Gas-Adsorption Selectivity. Institut de Physique et Chimie des Matériaux de Strasbourg, Université Louis Pasteur, Strasbourg, France PhD in Materials Chemistry (with distinction and congratulations) Supervisor, Dr. Pierre RABU Project: Multifunctional Hybrid Materials: Elaboration and Study of Magnetic and Luminescent Properties of Hydroxide-Based Layered Compounds. Université Louis Pasteur, Strasbourg, France Diplômes d Etude Approfondie de chimie des métaux de transition et d ingénierie moléculaire (Master s Degree in transition metal chemistry and molecular engineering), with distinction Laboratoire de Chimie de Coordination, Strasbourg, France Supervisor, Dr. Pierre BRAUNSTEIN Project: Reactivity of new quinonic ligands with carbonyl metals. 1

2 June 2002 March - June 2002 June 2001 June 2000 Université Louis Pasteur, Strasbourg, France Maîtrise de Chimie (Bachelor s Degree in Chemistry), with distinction Departement de Química Inorgànica, Universitat de València, Spain Supervisor, Pr. Miguel JULVE OLCINA Erasmus Project: Synthesis of transition metal complexes with new quinonic molecules and nitrogen-derivated ligands. Université Louis Pasteur, Strasbourg, France Licence de Chimie (Bachelor s Degree in Chemistry), with distinction Université Henry Poincaré, Nancy, France Diplôme d Etude Universitaire Générale en Sciences de la Matière (Associate s Degree in Materials Sciences) Knowledge and skills Synthesis: Coordination chemistry with transition metals and lanthanides, techniques of crystallogenesis (slow diffusion of solvents, solvothermal synthesis), reactions under inert atmosphere using Schlenck line or gloves box. Organic chemistry, ability to develop the synthesis of new molecules to use as ligands. Solid state chemistry, anionic and cationic exchange in tridimensional materials. Nanoparticles synthesis by soft chemistry or microwave route. Porous materials using templates (block copolymers) Experimental skills: Structural characterisations: Infra-Red, Raman and UV-vis spectroscopies, powder and single crystal X-Ray Diffraction, NMR in solution, Diffusion Light Scattering. Thin films elaboration: dip and spin coating methods Thermal behaviour: Thermo-Gravimetric Analysis coupled with Mass Spectrometer, Differential Scanning Calorimetry. Luminescent properties: absorption / emission spectroscopies in solution and solid state. Magnetic properties: Squid magnetometer and heat capacity. Gas and solvent adsorption: Surface area and porosimetry analyzer, high pressure hydrogen adsorption and environmental ellipsometry porosity. Partial job: Feb. to Nov. 2008: in charge of the single crystal X-Ray crystallography facility using the cyclotron beam to the Advanced Light Source in Lawrence Berkeley National Lab for the Department of Chemistry of Berkeley. 2

3 Languages: French, mother tongue; English, fluent, Spanish and German, scholar level. Computer skills: Microsoft Office, Origin, Win NMR, Chem Draw, Spartan, Cambridge crystallographic database, SHELX, APEX2, Sadabs, Saint, Platon, Bruker DIFFRAC plus EVA, U-Fit, Full Prof, Diamond, MSI Material Studio. Administrative and educational functions Elected representative of the post-graduate students at the Institut de Physique et Chimie des Matériaux de Strasbourg ( ). President of the Young Chemists Club, Alsace section, of the French Chemistry Society ( ). Co-organization of the first Journée, Société Française de Chimie Alsace, de communications des doctorants (Strasbourg, France, May 4, 2006). Co-responsible of five undergraduate students during phd studies and two graduate students during postdoctoral fellow in UC Berkeley. Publications 11. Selective Gas Adsorption in the Flexible Metal-Organic Frameworks Cu(BDTri)L (L = DMF, DEF). Aude Demessence, Jeffrey R. Long, submitted to Chem. Eur. J Synthesis, optical and magnetic properties of hybrid α,α -oligothiophenecarboxylates / transition metal hydroxide multilayered compounds. Aude Demessence, Abderrahim Yassar, Guillaume Rogez, Luciano Miozzo, Sophie De Brion, Pierre Rabu, submitted to J. Mater. Chem. (theme issue on Advanced Hybrid Materials ). 9. Elaboration and properties of hierarchically structured optical thin films of MIL-101(Cr) Aude Demessence, Patricia Horcajada, Christian Serre, Cédric Boissière, David Grosso, Clément Sanchez and Gérard Férey, Chem. Commun., 2009, Strong CO 2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine Aude Demessence, Deanna M. D Alessandro, Maw Lin Foo, Jeffrey R. Long, J. Amer. Chem. Soc., 2009, 131, Structure and Magnetic Properties of a New 1D Nickel(II) hydroxy-thiophenedicarboxylate Aude Demessence, Adel Mesbah, Michel François, Guillaume Rogez, Pierre Rabu, Eur. J. Inorg. Chem., 2009, 25,

4 6. Building Molecular and Layered Transition Metal Compounds Combining Magnetic and Optical Properties in «Materials, Membranes and Processes». A. Beghidja, A. Demessence, G. Rogez, P. Rabu, Ed. by G. Nechifor and M. Barboiu (Editura Printech, Bucharest, Romania), 2007, Structure and magnetic properties of a new Co II -Thiophenedicarboxylate coordination polymer showing unprecedented coordination. Aude Demessence, Guillaume Rogez, Richard Welter, Pierre Rabu, Inorg. Chem., 2007, 46, Grafting of thiophenecarboxylates into magnetic transition metal hydroxide layers. Aude Demessence, Guillaume Rogez, Pierre Rabu, Chem. Mater., 2006, 18, Effet du greffage de thiophène-carboxylates sur les propriétés magnétiques d hydroxydes lamellaires de métaux de transition. Aude Demessence, Guillaume Rogez et Pierre Rabu, l Actualité Chimique, 2006, 293, Influence of Magnetic Ordering on the Luminescence in a Layered Organic-Inorganic OPV-Ni(II) Compound. Jean-Michel Rueff, Jean-François Nierengarten, Pierre Gilliot, Aude Demessence, Olivier Cregut, Pierre Rabu, Chem. Mater. 2004, 16, Relocalisation of the system in benzoquinonediimines induced by metal coordination. Pierre Braunstein, Aude Demessence, Olivier Siri, Jean-Philippe Taquet, Comptes Rendus de Chimie, 2004, 7(8-9), Participation to conferences 19. Colloidal Route Towards Optical Thin Films of Nanoporous Metal-Organic Frameworks (Poster) Aude Demessence, Patricia Horcajada, Christian Serre, David Grosso, Cédric Boissière, Clément Sanchez and Gérard Férey Nanosciences in Ile de France, 3 rd Summer school, le Tremblay-sur-Mauldre, June 21-26, Microporous Metal-Organic Frameworks for Selective Gaz Adsorption (Oral) Aude Demessence Colloidal Route Towards Optical Thin Films of Nanoporous Metal-Organic Frameworks (Poster) Aude Demessence, Patricia Horcajada, Christian Serre, David Grosso, Cédric Boissière, Clément Sanchez and Gérard Férey GECOM-CONCOORD, Albé, France, May 24-29, Metal-Organic Frameworks for Selective Gas Adsorption Aude Demessence Invited talk by Pierre Rabu at IPCMS Strasbourg, April 6,

5 16. Metal-Organic Frameworks for Selective Gas Adsorption Aude Demessence Invited talk by Rodolphe Clérac and Corine Mathonière at CRPP Bordeaux, March 6, Hydrogen storage in microporous metal-organic frameworks with exposed metal sites (Oral) Mircea Dinca, Steven S. Kaye, Hye Jin Choi, Aude Demessence, Satoshi Horike, Leslie J. Murray, and Jeffrey R. Long The 237th ACS National Meeting, Salt Lake City, UT, March 22-26, Hydrogen storage in microporous metal-organic frameworks with exposed metal sites (Oral) Mircea Dinca, Steven S. Kaye, Hye Jin Choi, Aude Demessence and Jeffrey R. Long The 235th ACS National Meeting, New Orleans, LA, April 6-10, Hydrogen storage in water stable and flexible microporous triazole-based metal-organic frameworks (Poster) Aude Demessence and Jeffrey R. Long UCSB-MPG Workshop on Inorganic Materials for Energy Conversion, Storage and Conversion, UCLA Lake Arrowhead, CA USA, February 19-22, New Hybrid O/I Systems with Giant Coercive Fields: Oligo-thiophenecarboxylate-Based Cobalt(II) Hydroxides (Poster) Aude Demessence, Abderrahim Yassar, Guillaume Rogez, Pierre Rabu European Conference on Molecular Magnetism, Tomar, Portugal, October 10-15, Les hydroxydes lamellaires de métaux de transition, des matériaux hybrides magnétiques et luminescents? (Oral) Aude Demessence, Pierre Rabu, Guillaume Rogez, Abderrahim Yassar Colloque Matériaux Hybrides Organisés Multifonctionnels, La Grande Motte, France, May 9-11, Les hydroxydes lamellaires de métaux de transition, des matériaux hybrides magnétiques et luminescents? (Oral) Aude Demessence, Pierre Rabu, Guillaume Rogez, Abderrahim Yassar Journée, Société Française de Chimie Alsace, de communications des doctorants, Strasbourg, France, May 4, New Hybrid O/I Systems with Giant Coercive Fields: Oligothiophenedicarboxylate-Based Cobalt(II) Hydroxides (Poster) Aude Demessence, Pierre Rabu, Guillaume Rogez, Abderrahim Yassar First France-Japan Advanced School on Chemistry and Physics of Molecular Materials, Rennes, France, March 19-23, Organic/Inorganic transition metal-thiophene based layered materials: synthesis, structure and magnetic properties. (Poster) 5

6 Aude Demessence, Guillaume Rogez and Pierre Rabu EuroChem in Vandoeuvres-les-Nancy, France, August 28-September 1, Prize of the best poster 7. Effet du greffage de thiophène-carboxylates sur les propriétés magnétiques d hydroxydes lamellaires de métaux de transition. (Oral) Aude Demessence, Guillaume Rogez et Pierre Rabu Réunion du GFECI 2005 (Groupe Français d Etude des Composés d Insertion), Aubière, France, June 9-10, Insertion of thiophenecarboxylates into transition metal hydroxides and influence on their magnetic properties. (Poster) Aude Demessence, Guillaume Rogez, Pierre Rabu ISIC 13 (13 th International Symposium on Intercalation Compounds), Clermont-Ferrand, June 6-9, Organic/Inorganic transition metal-thiophene based layered materials: synthesis, structure and magnetic properties. (Poster) Aude Demessence, Guillaume Rogez and Pierre Rabu EMRS 2005 Spring Meeting, Strasbourg, France, May 31- June 3, Insertion of thiophenecarboxylates into transition metal hydroxides and their magnetic properties. (Poster) Aude Demessence, Guillaume Rogez and Pierre Rabu Congrès de la Société Française de Chimie, Grand Est 2005, Mulhouse, France, March 22-23, Prize of the best poster 3. Influence de l ordre magnétique sur la luminescence de matériaux hybrides lamellaires. (Oral) Aude Demessence, Jean-Michel Rueff, Jean-François Nierengarten, Pierre Gilliot, Olivier Cregut, Marc Drillon, Guillaume Rogez et Pierre Rabu 2 ème Journée du GEMIL (Groupe d Etude des Matériaux Inorganiques Luminescents), Paris, France, October 29, Influence of magnetic ordering on the luminescence in layered organic-inorganic materials. (Poster) Jean-Michel Rueff, Jean-François Nierengarten, Pierre Gilliot, Aude Demessence, Marc Drillon and Pierre Rabu MAGEL 3 (The 3 rd Magneto Electronic International Symposium), La Rochelle, France, June 15-19, Effet du greffage de thiophène-carboxylates sur les propriétés magnétiques d hydroxydes lamellaires de métaux de transition. (Poster) Aude Demessence, Guillaume Rogez, Pierre Rabu Réunion du GFECI (Groupe Français d Etude des Composés d Insertion), Lacanau, France, March 23-25,

7 Collaborations: Dr. Jean-François NIERENGARTEN Laboratoire de Chimie de Coordination Toulouse France Phone Dr. Abderrahim YASSAR ITODYS Université Paris7-Denis Diderot Paris - France [email protected] Phone Dr. Simon J. TEAT Advanced Light Source Lawrence Berkeley National Lab Berkeley, CA - USA [email protected] Phone: Members of PhD defence: Pr. Silvio DECURTINS Department of Chemistry and Biochemistry University of Berne Berne - Switzerland [email protected] Phone: Dr. Fabrice LEROUX Laboratoire des Matériaux Inorganiques, Université Blaise Pascal Aubière - France. [email protected] Phone: Dr. Clément SANCHEZ Laboratoire de Chimie de la Matière Condensée Collège de France Paris - France [email protected] Phone: References: Dr. Clément SANCHEZ Laboratoire de Chimie de la Matière Condensée Collège de France Paris - France [email protected] Phone: Dr. Christian SERRE Institut Lavoisier Université de Versailles Saint-Quentin-en-Yvelines Versailles France [email protected] Phone Pr. Jeffrey R. LONG University of California Department of Chemistry Berkeley, CA - USA [email protected] Phone: Dr. Pierre RABU and Dr. Marc DRILLON Institut de Physique et Chimie des Matériaux de Strasbourg Strasbourg - France [email protected] Phone [email protected] Phone Dr. Pierre BRAUNSTEIN Laboratoire de Chimie de Coordination - Institut Le Bel Strasbourg - France [email protected] Phone Pr. Miguel JULVE OLCINA Departement de Química Inorgànica, Facultat de Química Burjassot - Valencia - Spain [email protected] Phone: Pr. Philippe TUREK Chimie Physique Moléculaire et Spectroscopie Institut Le Bel Strasbourg - France [email protected] Phone: